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Asakura, Toshihide; Kim, S.-Y.; Morita, Yasuji; Ozawa, Masaki*
Journal of Nuclear and Radiochemical Sciences, 6(3), p.267 - 269, 2005/12
An electrolytic extraction (EE) method, i.e. electro-reductive deposition, of Tc from nitric acid aqueous solution was studied for future reprocessing. After 30 min of constant potential electrolysis by carbon electrode at -0.3 V vs. SSE (Standard Silver Electrode), Tc concentration in 3 M nitric acid decreased to 93 % of the initial value, which corresponds to 7 % of deposition. With co-existence of Pd, the value reached to 15 % of deposition equivalent by electrolysis at 0.0 V vs. SSE for 60 min. An acceleration effect of Pd on Tc deposition (promoter effect) was suggested. The concentration, however, increased to the initial value after further electrolysis and competing re-dissolution of deposited Tc was also suggested. In cyclic voltammetry measurements, it was found that the deposit from Tc-Pd-Ru-Rh solution dissolved easier than that from Pd-Ru-Rh did. In electrolyzed Tc solution, an absorption peak at 482 nm was found. It can be attributed to the complex with nitrite anion, and the complex formation is proposed as one possible mechanism of Tc re-dissolution.
Muramatsu, Kazuhiro; Sai, Kazunori*
JAERI-Data/Code 2002-017, 101 Pages, 2002/08
A visualization system on the Earth Simulator is developped. The system enables users to see a graphic representation of simulation results on a client terminal simultaneously with them being computed on the Earth Simulator. Moreover, the system makes it possible to change parameters of the calculation and its visualization in the middle of calculation. The graphical user interface of the system is constructed on a Java applet. Consequently, the client only needs a web browser, so it is independent of operating systems. The system consists of a server function, post-processing function and client function. This report describes mainly the usage of the server and post-processing functions.
Kosako, Kazuaki*
JAERI-M 90-199, 114 Pages, 1990/11
no abstracts in English